| P | V | P | S | GF | GS | |
|---|---|---|---|---|---|---|
| 24 | 10 | 7 | 7 | 31 | 27 |
| P | V | P | S | GF | GS | ||
|---|---|---|---|---|---|---|---|
 Coppa Intertoto | 4 | 2 | 1 | 1 | 5 | 3 | |
Europa League | 12 | 5 | 4 | 3 | 15 | 13 | |
Champions League | 8 | 3 | 2 | 3 | 11 | 11 |
V | 2022-03-16 | Juventus |  | 0-3 |  | Villarreal | 1/8 | ||
P | 2022-02-22 | Villarreal | | 1-1 | | Juventus | 1/8 | ||
V | 2021-12-09 | Atalanta |  | 2-3 | | Villarreal | GrpF | ||
P | 2021-09-14 | Villarreal | | 2-2 | | Atalanta | GrpF | ||
V | 2017-02-23 | Roma |  | 0-1 | | Villarreal | 1/16 | ||
S | 2017-02-16 | Villarreal | | 0-4 | | Roma | 1/16 | ||
P | 2016-02-25 | Napoli |  | 1-1 | | Villarreal | 1/16 | ||
V | 2016-02-18 | Villarreal | | 1-0 | | Napoli | 1/16 | ||
S | 2011-12-07 | Villarreal | | 0-2 | | Napoli | GrpA | ||
S | 2011-09-27 | Napoli | | 2-0 | | Villarreal | GrpA | ||
V | 2011-02-24 | Villarreal | | 2-1 | | Napoli | 1/16 | ||
P | 2011-02-17 | Napoli | | 0-0 | | Villarreal | 1/16 | ||
V | 2009-11-05 | Villarreal | | 4-1 |  | Lazio | GrpG | ||
S | 2009-10-22 | Lazio | | 2-1 | | Villarreal | GrpG | ||
P | 2007-10-25 | Villarreal | | 1-1 |  | Fiorentina | GrpC | ||
V | 2006-04-04 | Villarreal | | 1-0 |  | Internazionale | QF | ||
S | 2006-03-29 | Internazionale | | 2-1 | | Villarreal | QF | ||
P | 2004-10-21 | Lazio | | 1-1 | | Villarreal | GrpE | ||
S | 2004-03-25 | Roma | | 2-1 | | Villarreal | 4T | ||
V | 2004-03-11 | Villarreal | | 2-0 | | Roma | 4T |
